Phase shifting, or phasing, is the process by which objects and materials can be placed out of phase from normal substances which can cause effects from invisibility to allowing objects to completely pass through each other. In 2269 the crew of the USS Enterprise was accidentally put out of phase while testing a prototype cloaking device developed by Starfleet Intelligence based on a Romulan cloaking device stolen by the Enterprise previously. (TOS comic: "The Enterprise Experiment, Part 1")
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