They can potentially be captured from their trainer and then purified. To purify a shadow Pokémon just walk around with it; its heart gauge goes down similarly to how an egg is normally hatched. When the gauge is at 0 it will say "Undo the final lock!" This is done at the Relic Stone in Origin City. The heart gauge can also be brought down with items called scents. These are purchasable in Antares Town in the house to the right of the Pokémon Center.
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