Unless you start with a character that has more than just the basic 25 on each skill, it will be impossible to level all of them to a max of 100. Down below when it says a Stat that is above 100, that is due to Armor or Weapon that has been Master Crafted. Weapons can have Accuracy, Reload, or Critical hit up to 8 per weapon. Since you get 3 weapons, this allows for a possible bonus of 24 in each category. Armor gives bonuses on Endurance and Agility, up to 24 in both categories.