She is first seen in "Chuck Versus the Wedding Planner", where she is sitting in Chuck's Apartment discussing the wedding plans with Chuck and Sarah. Unable to decide if the color theme for the wedding is too communist, Sarah tries to phone Daphne but find out the phone number is no longer in service. Worried Sarah and Chuck go down to the address they had been given by Daphne only to find out it's fake and that Daphne has run away with the money they give her, they've been conned.