Selected in the first round, fourth overall, in the 1996 NHL Entry Draft by the Washington Capitals, Volchkov was a talented right-winger who put up impressive offensive numbers while playing junior hockey for the Barrie Colts. Washington management were well aware of Volchkov's attitude issues, but decided that his talent overshadowed any potential problems. Offensively gifted, the enigmatic Volchkov never reached his potential as a pro due to his poor attitude. In one incident while playing with the Capitals' minor league affiliate Portland Pirates, he walked out on the team during a playoff game.