She played for the Collège Édouard-Montpetit in Québec. She was named the Collégial AA top goaltender in 2008-09 and helped lead the school to the Collègial AA championship. During the 2009-10 campaign, Douville led the Collègial AA in Goals Against Average. In addition, she led the school to the regular season and playoff titles. Douville was a Montreal Canadiens scholarship holder in 2010 from the Quebec Foundation for Athletic Excellence.